期刊
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
卷 61, 期 33, 页码 7889-7895出版社
AMER CHEMICAL SOC
DOI: 10.1021/jf4014718
关键词
sheath-flow probe electrospray ionization mass spectrometry; pesticide analysis; real-time
资金
- Japan Science and Technology Agency (JST)
- Japan Society for the Promotion of Science (JSPS)
- Grants-in-Aid for Scientific Research [13F03034] Funding Source: KAKEN
For the real time and direct analysis of chemical constituents from living beings and dry sample, sheath-flow probe electrospray ionization mass spectrometry (SF-PESI-MS) has been newly developed. The components from dry or semidry biological tissues can be extracted using the solvent and picked up by the needle for electrospray. This technique was applied to real-time pesticide analysis of living plants. The results have been validated with that of a well-known system, liquid extraction surface analysis mass spectrometry (LESA-MS). It is demonstrated that SF-PESI-MS can produce reasonable ionization efficiency, which is confirmed by LESA-MS.
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