期刊
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
卷 57, 期 19, 页码 8860-8867出版社
AMER CHEMICAL SOC
DOI: 10.1021/jf901599j
关键词
Securidaca; saponins; oviposition deterrent; Sitophilus; Callosobruchus; bruchid
资金
- Medical Research Council [MC_U117533887] Funding Source: Medline
- Medical Research Council [MC_U117533887] Funding Source: researchfish
- MRC [MC_U117533887] Funding Source: UKRI
Powdered dry root bark of Securidaca longepedunculata was mixed with maize and cowpea and effectively reduced the numbers of Sitophilus zeamais and Callosobruchus maculatus emerging from these commodities, respectively, more than 9 months after treatment. This effect was reciprocated in grain treated with a methanol extract of the root bark, indicating that compounds were present that were oviposition deterrents or directly toxic to the adults or larvae. Two new bisdesmosidic saponins, 3-O-beta-D-glucopyranosyl-28-O(alpha-L-arabinopyranosyl-(1 -> 3)-beta-D-xylopyranosyl-(1 -> 4)[beta-D-apiofuranosyl-(1 -> 3)]-alpha-L-rhamnopyranosyl-(1 -> 2)-[4-O-(4-methoxycinnamoyl-beta-D-fucopyranosyl)])-medicagenic acid (securidacaside A) and 3-O-beta-D-glucopyranosyl-28-O(alpha-L-arabinopyranosyl-(1 -> 3)-beta-D-xylopyranosyl-(1 -> 4)-[beta-D-apiofuranosyl-(1 -> 3)]-alpha-L-rhamnopyranosyl-(1 -> 2)-[4-O-(3,4,5-trimethoxy-(E)-cinnamoyl-beta-D-fucopyranosyl)])-medicagenic acid (securidacaside B), were isolated from the methanol extract of the roots of S. longepedunculata and characterized by spectroscopic methods. Securidacaside A, which occurred as (E)- and (Z)-regioisomers, showed deterrency and toxicity toward C. maculatus and S. zeamais and could contribute to the biological activity of the methanol extract. The potential to optimize the use of this plant for stored product protection using water extracts, which would be appropriate technology for target farmers, is discussed.
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