期刊
JAPANESE JOURNAL OF APPLIED PHYSICS
卷 47, 期 3, 页码 1662-1666出版社
IOP PUBLISHING LTD
DOI: 10.1143/JJAP.47.1662
关键词
manganese oxide film; cyclic voltammetry; hydration; surface properties; energy storage
Nanometer-scale manganese oxide films were synthesized at various temperatures in the range of 60-150 degrees C using the hydrothermal electrochemical deposition method. Field-emission scanning electron microscopy (FE-SEM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) were used to verify that the deposits were tri- and divalent hydrous manganese oxides. The electrochemical performance of manganese oxide films was examined by cyclic voltammetry (CV) in the range of 0.0-1.0 V [versus saturated calomel electrode (SCE)] in 0.1 M Na2SO4 solution at 25 degrees C. The specific capacitance (SC) increased with decreasing synthesis temperature, with a maximum value of approximately 244 F.g(-1) at 60 degrees C. Crystalline manganese oxide prepared at 150 degrees C improved stability of capacitive performance, which only decreased by 4% after 800 cycles. The SC depended not only on the surface morphology but also on the amount of hydration in the manganese oxide structure. The deposited manganese oxide has the chemical formula Mn3O4 center dot nH(2)O (n similar to 1.2), as established using thermogravimetric and differential thermal analysis (TG/DTA).
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