期刊
MONATSHEFTE FUR CHEMIE
卷 146, 期 12, 页码 2029-2040出版社
SPRINGER WIEN
DOI: 10.1007/s00706-015-1563-z
关键词
N-Heterocycle; 3-(2-Bromoacetyl)-2H-chromen-2-one; 1,3-Dipolar cycloaddition; Pyrrolo-fused heterocycles
资金
- Sectorial Operational Programme Human Resources Development of the Ministry of European Funds [POSDRU/159/1.5/S/134398]
A variety of new pyrrolo-fused heterocyclic systems bearing a 3-carbonylchromen-2-one moiety on the pyrrole rings was obtained based on 1,3-dipolar cycloaddition reactions of corresponding cycloimmonium-ylides, generated in situ from the quaternary salts of several N-heterocycles with 3-(2-bromoacetyl)-2H-chromen-2-one, with electron-deficient alkynes. The synthetic strategies were both one-pot, three-component and classical multistep 1,3-dipolar cycloaddition reactions. The all newly synthesized compounds were structurally characterized by elemental analysis, IR and NMR spectroscopy.
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