期刊
MOLECULES
卷 20, 期 4, 页码 5812-5824出版社
MDPI AG
DOI: 10.3390/molecules20045812
关键词
diffusion coefficients; transport properties; sodium hyaluronate; Taylor dispersion; Huggins constant; limiting viscosity number
资金
- FCT [PTDC/AAC-CLI/118092/2010]
- Coimbra Chemistry Centre from the FCT [Pest-OE/QUI/UI0313/2014]
- Centre of Polymer Systems [CZ.1.05/2.1.00/03.0111]
- TBU in Zlin - specific university research and national budget of Czech Republic [IGA/FT/2013/015, IGA/FT/2014/018]
- [SFRH/BD/72305/2010]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/72305/2010] Funding Source: FCT
Mutual diffusion coefficients, D, were determined for aqueous solutions of sodium hyaluronate (NaHy) at 25 degrees C and concentrations ranging from 0.00 to 1.00 gdm(-3) using the Taylor dispersion technique. From these experimental data, it was possible to estimate some parameters, such as the hydrodynamic radius R-h, and the diffusion coefficient at infinitesimal concentration, D-0, of hyaluronate ion, permitting us to have a better understanding of the structure of these systems of sodium hyaluronate in aqueous solutions. The additional viscosity measurements were done and Huggins constant, k(H), and limiting viscosity number, [], were computed for interaction NaHy/water and NaHy/NaHy determination.
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