期刊
MOLECULES
卷 20, 期 12, 页码 22635-22644出版社
MDPI AG
DOI: 10.3390/molecules201219874
关键词
hypervalent iodine; (diacetoxyiodo)arenes; metathesis
资金
- National Science and Engineering Research Council (NSERC) of Canada
- Canada Foundation for Innovation (CFI)
- FRQNT Centre in Green Chemistry and Catalysis (CGCC)
- Universite de Sherbrooke
The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetoxyiodo)arenes. A computational study is provided to rationalize the results observed.
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