期刊
ISRAEL JOURNAL OF CHEMISTRY
卷 53, 期 8, 页码 511-520出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201300045
关键词
hydrogen bonding; main-chain supramolecular polymer; noncovalent interaction; side-chain supramolecular polymer; supramolecular polymerization
资金
- National Institute of Health [GM-087448]
- National Science Foundation [CHE-1012212]
- Chonnam National University
- Direct For Mathematical & Physical Scien [1012212] Funding Source: National Science Foundation
Supramolecular polymer chemistry has emerged as a major research focus within polymer science, because of the potential to improve material properties, through the combination of noncovalent interactions and synthetic polymers. As a supramolecular handle, the most useful noncovalent interaction is hydrogen bonding, which has been used extensively, because of advantages such as synthetic accessibility, directionality, fidelity, and, most importantly, responsiveness to external stimuli. This review introduces recent advances in the development of hydrogen bonding modules that can be useful for creating a variety of supramolecular polymers. Furthermore, we present selected examples of hydrogen bonded supramolecular polymers from the literature, by dividing them into three categories: supramolecular polymers assembled from small molecules, and main-chain and side-chain supramolecular polymers.
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