期刊
ISRAEL JOURNAL OF CHEMISTRY
卷 52, 期 1-2, 页码 41-52出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201100091
关键词
conjugation; cross-coupling; materials science; paracyclophane; small molecules
资金
- Ministero dell'Istruzione, dell'Universita e della Ricerca (MIUR)
- University of Perugia through the FIRB [RBFR08TTWW, RBFR08 J78Q]
- PRIN
In the search for molecules for organic photonics and electronics, several strategies have been used to modulate physical and chemical properties of [2.2]paracyclophane derivatives by sequential functionalization of their three-dimensional cores. This review summarizes the major design and synthetic strategies for tuning paracyclophane-containing small molecules by introducing various moieties featuring (hetero)aromatic rings directly connected to each other, as well as alternating (hetero)aryl and ethylene or ethynylene units. Several examples are presented that elucidate the structural, optical, and electronic consequences of incorporating these fragments in the aromatic decks, particularly relating to applications in organic optoelectronics.
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