Side-Chain Metallocene-Containing Polymers by Living and Controlled Polymerizations

This review summarizes recent work on side-chain metallocene-containing polymers prepared by controlled and living polymerizations, which include living anionic polymerization (LAP), ring-opening metathesis polymerization (ROMP) and controlled radical polymerization (CRP) such as atom transfer radical polymerization (ATRP), reversible addition fragmentation chain transfer polymerization (RAFT), and nitroxide-mediated polymerization (NMP). The majority of efforts in the field are focused on side-chain ferrocene-containing polymers, while cobaltocenium-containing polymers have recently started to draw attention. Future direction on the development of other metallocene-containing polymers is discussed.