期刊
ISRAEL JOURNAL OF CHEMISTRY
卷 51, 期 7, 页码 769-780出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201100049
关键词
dimeric capsules; hydrogen bonds; resorcin[4]arenes; self-assembly; x-ray structures
资金
- Academy of Finland [212588, 218325]
- University of Jyvaskyla
Supramolecular chemistry research is focused on the study of weak non-covalent intermolecular that is, supramolecular - interactions as the driving force in self-assembly and molecular recognition. Dimeric resorcin[4]arenes capsules have been a focus of our research for the last 15 years. This review describes the solid state complexation studies of unsubstituted phenolic resorcin[4]arenes and pyrogall[4]arenes towards the formation of dimeric capsules and assemblies using ionic and neutral species as guest molecules and templates. The multitude of different crystal structures obtained during these studies demonstrates the versatile nature of resorcin[4]arenes and pyrogall[4]arenes (2-hydroxy-resorcin[4]arenes) as supramolecular hosts in crystal engineering.
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