期刊
ISRAEL JOURNAL OF CHEMISTRY
卷 50, 期 3, 页码 374-381出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201000041
关键词
microelectrodes; nanostructures; numerical simulations; SECM; thin films
The advent of microelectrodes has opened new areas of study and significantly improved the quality of electroanalytical data. Using examples from the author's work, this brief review describes contributions made by microelectrodes to the field of electroanalytical chemistry. Several fundamental studies, ranging from the development of theoretical approaches for the scanning electrochemical microscope to the determination of the mechanism and kinetics of coupled chemical reactions, are recalled. Most involve a serious dose of numerical simulations. Several applied studies illustrate the development of experimental approaches, in particular the development of nanostructured microelectrodes, to improve the reliability and quality of the microelectrode response for analytical measurements and sensing.
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