The NASICON solid solution Li1-x La x /3Zr2(PO4)3: optimization of the sintering process and ionic conductivity measurements

The Li1-x La (x) Zr-/3(2)(PO4)(3) NASICON-type compounds (0 a parts per thousand currency signaEuro parts per thousand x a parts per thousand currency signaEuro parts per thousand 1) have been synthesized in powder form by a sol-gel method and sintered for ionic conductivity measurements. In order to improve the compactness of the ceramic without decomposition of the compound, several sintering processes have been tested for one member of the solid solution (x = 0.6): the use of sintering aids (ZnO, B2O3, TiO2 and LiNO3), a ball-milling of the synthesized powder, a flash heating, high isostatic pressure, and spark plasma sintering. Finally, a satisfactory compactness of 85% is obtained compared to the referenced value (63%) obtained by uniaxial and isostatic pressing. The ionic conductivity study was performed by impedance spectroscopy. It shows that, despite the formation of vacancies, the substitution Li+-> 1/3 La3+ + 2/3 a- has unfortunately no influence on the conduction for 0 a parts per thousand currency signaEuro parts per thousand x a parts per thousand currency signaEuro parts per thousand 0.7 since the ionic conductivity remains identical to the LiZr2(PO4)(3) one. For higher x values, the ionic conductivity strongly decreases.