期刊
INTERNATIONAL JOURNAL OF THERMOPHYSICS
卷 34, 期 2, 页码 226-239出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10765-013-1404-4
关键词
DSC; Propellant's stabilizers; Semi-empirical models; Solid-liquid equilibria
Solid-liquid equilibria for three binary mixtures of 2-nitrodiphenylamine (1) + diphenylamine (2), ethyl centralite (1) + N-ethyl-4-nitro-N-nitrosoaniline (2), and 2,2-dinitrodiphenylamine (1) + N-ethyl-4-nitro-N-nitrosoaniline (2) were measured using a differential scanning calorimeter. Simple eutectic behaviors for these systems were observed. The experimental results were correlated by means of original and modified NRTL, Wilson, and UNIQUAC equations. The root-mean-square deviations of the solubility temperatures for all measured data vary from 0.63 K to 3.73 K and depend on the particular model used. The best solubility correlation was obtained with the UNIQUAC model.
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