期刊
INTERNATIONAL JOURNAL OF THERMOPHYSICS
卷 30, 期 4, 页码 1257-1269出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10765-009-0641-z
关键词
Differential scanning calorimetry; Phase change material; Salt hydrate; T-history method
Phase change materials (PCMs) are thermal storage materials with a high storage density for small temperature range applications. In the design of latent heat storage systems, the enthalpy change of the PCM has to be known as a function of temperature with high precision. During dynamic measurements, the sample is not in thermal equilibrium, and therefore the measured value is not the equilibrium value. The influence of non-equilibrium on the measurement results can be quantified by doing measurements during heating and cooling with any measurement instrument. Measurements carried out by differential scanning calorimetry (DSC) and by the T-history method are presented and discussed. To characterize encapsulated PCM objects, measurements on the whole objects should be carried out. A measurement setup for this purpose is also presented. The obtained precision meets typical application requirements, and good agreement between results obtained with the different methods is demonstrated.
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