期刊
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS
卷 61, 期 1-4, 页码 177-198出版社
TAYLOR & FRANCIS AS
DOI: 10.1080/00914037.2011.557805
关键词
graft; hydrogel; pH-sensitive; rapid response; thermosensitive
资金
- Gansu Province Project of Science and Technologies [0804WCGA130]
- National Natural Science Foundation of China [J0730425]
- Organizing Committee of the Chun-Tsung Endowment
The dual-sensitive, comb-type grafted hydrogels were synthesized by grafting polymeric chains with freely mobile ends, which were composed of both N,N-diethylacrylamide (DEA) and (2-dimethylamino) ethyl methacrylate (DMAEMA), onto the backbone of crosslinked poly(DEA-co-DMAEMA) networks. The structure of the poly(DEA-co-DMAEMA) macromonomer was characterized by Nuclear Magnetic Resonance (H-1 NMR) and Fourier transform infrared spectroscopy (FTIR). The effects of the feed components, temperature, and pH on the swelling behavior of the hydrogels were studied. With the increase of the poly(DEA-co-DMAEMA) macromonomer content, the thermo- and pH-sensitivity of the hydrogels improved. The G-PDD hydrogels exhibited improved thermo- and pH-sensitive characteristics, such as faster deswelling and reswelling rates and great oscillating deswelling/swelling behavior, and the level of improvement depended on the poly(DEA-co-DMAEMA) macromonomer content. The proposed dual thermo- and pH-sensitive, comb-type grafted poly(DEA-co-DMAEMA) hydrogel has various potential applications.
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