期刊
INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION
卷 17, 期 6, 页码 444-457出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/1023666X.2012.696051
关键词
Particle swelling; Seeded emulsions; Swelling at equilibrium; Swelling kinetics
资金
- University of Guadalajara
- Conacyt [214584]
In seeded emulsion (co)polymerization, the evolution throughout the reaction of the monomer concentration(s) in the latex particles affects its final properties, such concentrations resulting from the balance between the swelling and polymerization kinetics. Thus, the swelling behavior of 180 latexes was determined, by systematically modifying: (a) the water/polymer and the monomer/polymer ratios, (b) the seed particle size, and (c) the type of swelling monomer. Trend curves correlating the monomer concentration in the particles at equilibrium conditions and the relative amount of monomer added to the system are proposed. In addition, for each system with slow swelling, its swelling kinetics is also reported.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据