期刊
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
卷 11, 期 10, 页码 3803-3845出版社
MDPI
DOI: 10.3390/ijms11103803
关键词
porous coordination polymer (PCP); metal-organic framework (MOF); gas adsorption; gas separation; structural transformation; gate phenomena; elastic layer-structure; clathrate formation
资金
- Japan Science for the Promotion of Science [19350100]
- Ministry of Education, Culture, Sports, Science and Technology, the Japanese Government
Coordination polymers (CPs) or metal-organic frameworks (MOFs) have attracted considerable attention because of the tunable diversity of structures and functions. A 4,4'-bipyridine molecule, which is a simple, linear, exobidentate, and rigid ligand molecule, can construct two-dimensional (2D) square grid type CPs. Only the 2D-CPs with appropriate metal cations and counter anions exhibit flexibility and adsorb gas with a gate mechanism and these 2D-CPs are called elastic layer-structured metal-organic frameworks (ELMs). Such a unique property can make it possible to overcome the dilemma of strong adsorption and easy desorption, which is one of the ideal properties for practical adsorbents.
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