期刊
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
卷 10, 期 9, 页码 3931-3936出版社
MDPI
DOI: 10.3390/ijms10093931
关键词
surface enhanced spectroscopy; energy transfer; optical theorem; plasmon modes
资金
- Agence Nationale de la Recherche (ANR) [PNANO 07-51]
The non-radiative coupling of a molecule to a metallic spherical particle is approximated by a sum involving particle quasistatic polarizabilities. We demonstrate that energy transfer from molecule to particle satisfies the optical theorem if size effects corrections are properly introduced into the quasistatic polarizabilities. We hope that this simplified model gives valuable information on the coupling mechanism between molecule and metallic nanostructures available for, e. g., surface enhanced spectroscopy signal analysis.
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