Preparation and characterization of nanoporous carbon-supported platinum as anode electrocatalyst for direct borohydride fuel cell

The nanoporous carbon (NPC) is synthesized by carbonization of metal-organic framework-5 (MOP-5, [Zn4O(bdc)(3)], bdc = 1,4-benzenedicarboxylate) with furfuryl alcohol (FA) as carbon source and used as the carrier of the anode catalyst for the direct borohydride-hydrogen peroxide fuel cell (DBHFC). Then the NPC-supported Pt anode catalyst (Pt/NPC) is firstly prepared by a modified NaBH4 reduction method. The obtained Pt/NPC catalyst is characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive spectrometry (EDS), cyclic voltammetry, chronopotentiometry, chronoamperometry and fuel cell test. The results show that the Pt/NPC is made up of the spherical Pt nanoparticles which disperse uniformly on the surface of the NPC with average size 2.38 nm, and exhibits 36.38% higher current density for directly borohydride oxidation than the Vulcan XC-72 carbon supported Pt (Pt/XC-72). Besides, the DBHFC using the Pt/NPC as anode electrocatalyst shows the maximum power density as high as 54.34 mW cm(-2) at 25 degrees C. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.