期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 207, 期 -, 页码 90-94出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2014.12.034
关键词
Metal-organic frameworks; Hydrogen sulfide; IR spectroscopy; Raman spectroscopy; X-ray diffraction
类别
资金
- EU FP-7 Framework NANO-MOF project [CP-IP 228604-2]
- Mega-grant of the Russian Federation Government [14.Y26.31.0001]
The interaction of H2S with FIKUST-1 and ZIF-8 MOFs has been studied by means of FT-IR, Raman, DRUV-Vis-NIR and PXRD techniques. At very low equilibrium pressure (below 5 mbar) a stepwise structural distortion is observed in both HKUST-1 and ZIF-8. At higher equilibrium pressures (20-60 mbar), PXRD technique, in particular, showed the structural destruction of HKUST-1 with formation of a covallite (CuS) phase and some structural distortion of ZIF-8. (C) 2015 Elsevier Inc. All rights reserved.
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