High-pressure torsion of TiFe intermetallics for activation of hydrogen storage at room temperature with heterogeneous nanostructure

TiFe is a potential candidate for the stationary hydrogen storage systems, but it requires initial activation to absorb hydrogen. This study shows that TiFe processed by high-pressure torsion (HPT) absorbs and desorbs 1.7 wt.% hydrogen at room temperature without activation. The absorption pressure decreases from 2 MPa in the first hydrogenation cycle to 0.7 MPa in the latter cycles. The HPT-processed TiFe exhibits heterogeneous microstructures composed of nanograins, coarse-grains, amorphous-like phases and disordered phases with a high hardness of similar to 1050 Hv. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.