期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 38, 期 28, 页码 12503-12508出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2013.07.033
关键词
Fracture toughness; Critical stress intensity factor; Hydrogen embrittlement; Hydrogen gas
资金
- Innovation Project for College Graduates of Jiangsu Province in China [CXZZ11_0335]
Fracture toughness or critical stress intensity factor of many steels can be reduced by hydrogen gas. In this paper, a simple quantitative model to predict the fracture toughness of steels in gaseous hydrogen is proposed. This model is based on the assumption that fracture of a cracked body occurs when the maximum principal stress ahead of the crack tip reaches the critical cohesive stress for crack initiation. The critical stress is inversely proportional to the accumulated hydrogen concentration. The notion is that the crack will initiate at the elastic-plastic boundary ahead of the crack tip when hydrogen concentration reaches a maximum value after a long-term hydrogen diffusion assisted by the hydrostatic stress. The model describes the dependence of fracture toughness on hydrogen pressure, temperature and yield strength of steels. It can be used to quantitatively predict fracture toughness of steels in hydrogen gas, particularly in high pressure. Some experimental data reported in literature were used to validate the model, and a good agreement was obtained. Crown Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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