Effect of CaO on tar reforming to hydrogen-enriched gas with in-process CO2 capture in a bubbling fluidized bed biomass steam gasifier

Previous studies showed that calcium oxide (CaO), when added to a biomass steam gasifier, could play the role of both CO2 sorbent and tar reforming catalyst, and thereby produce more hydrogen. However, most of these works focused on the former role with little attention to tar reforming aspect of CaO. Therefore, this work aims primarily at studying the tar reforming effect of in-bed CaO. To this end, an in-depth analysis of the effect of CaO on tar yield and composition is presented. The present work also studies the role of CaO as a CO2 sorbent to enhance hydrogen production from steam gasification of biomass in a bubbling fluidized bed. The influence of different operating parameters, temperature (T) and steam to biomass (S/B) ratio, as well as the effect of using in-bed CaO on gas and tar production is investigated. Results show that the maximum H-2 and minimum CO2 concentration of 63.07% and 18.68%, respectively are obtained at T = 650 degrees C and S/B = 3.41. The maximum H-2 yield of 256.81 ml g(-1)-biomass was obtained at T = 700 degrees C and S/B = 3.41, at which the minimum tar content of 6.45 g N m(-3) was also received. Compared to a bed of sand alone, a 20% higher H-2 concentration, an almost double H-2 yield and a 67% reduction in tar content were obtained when a bed of CaO was used. Moreover, shifting the tar species from higher to fewer ring structures as a result of in-bed CaO can reduce tar dew point by 11 degrees C and tar carcinogenic potential by almost 60%. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.