H2 production from a single stage water-gas shift reaction over Pt/CeO2, Pt/ZrO2, and Pt/Ce(1-x)Zr(x)O2 catalysts

To develop a single stage water-gas shift reaction (WGS) catalyst for compact reformers, Pt/CeO2, Pt/ZrO2, and Pt/Ce(1-x)Zr(x)O2 catalysts have been applied for the target reaction. The CeO2/ZrO2 ratio was systematically varied to optimize Pt/Ce(1-x)Zr(x)O2 catalysts. Pt/CeO2 showed the highest turnover frequency (TOF) and the lowest activation energy (E-a) among the catalysts tested in this study. It has been found that the reduction property of the catalyst is more important than the dispersion for a single stage WGS. Pt/CeO2 catalyst also showed stable catalytic performance. Thus, Pt/CeO2 can be a promising catalyst for a single stage WGS for compact reformers. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.