4.7 Article

La-doped SrTiO3 interconnect materials for anode-supported flat-tubular solid oxide fuel cells

期刊

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 37, 期 5, 页码 4319-4327

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2011.10.125

关键词

Anode-supported solid oxide fuel cell; Flat-tubular cell; Interconnect; Strontium titanate; Sr deficiency

资金

  1. Materials Technology Development Program (Development of Highly Conductive Nanocomposite Materials for Interconnects) [10037312]
  2. Ministry of Knowledge Economy (MKE, Korea)

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An interconnect layer in an anode-supported flat-tubular solid oxide fuel cell connects electrically unit cells and separates fuel from oxidant in the adjoining cells. Nano-sized La-doped SrTiO3 for the interconnect is synthesized in this study by the Pechini method using citric acid. The materials with stoichiometric and Sr-deficient compositions are prepared and sintered in an oxidizing atmosphere. The synthesized fine powders exhibit high sinterability, leading to near-full densification. The Sr deficiency plays a crucial role in mechanical, electrical and thermal expansion properties. The interconnect is coated using the synthesized powder on a porous flat-tubular anode support by a screen printing process. The thin and dense layer is obtained after co-sintering in air, and the interconnect/anode interface remains intact upon reduction. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

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