Life cycle assessment of hydrogen supply chain with special attention on hydrogen refuelling stations

The controversial and highly emotional discussion about biofuels in recent years has shown that greenhouse gas(2) (GHG) emissions can only be evaluated in an acceptable way by carrying out a full life cycle assessment (LCA) taking the overall life cycle including all necessary pre-chains into consideration. Against this background, the goal of this paper is it to analyse the overall life cycle of a hydrogen production and provision. A state of the art hydrogen refuelling station in Hamburg/Germany opened in February 2012 is therefore taken into consideration. Here at least 50% hydrogen from renewable sources of energy is produced on-site by water electrolysis based on surplus electricity from wind (mainly offshore wind parks) and water. The remaining other 50% of hydrogen to be sold by this station mainly to hydrogen-fuelled buses is provided by trucks from a large-scale production plant where hydrogen is produced from methane or glycerol as a by-product of the biodiesel production. These two pathways are compared within the following explanations with hydrogen production from biomass and from coal. The results show that - with the goal of reducing GHG emissions on a life cycle perspective - hydrogen production based on a water electrolysis fed by electricity from the German electricity mix should be avoided. Steam methane reforming is more promising in terms of GHG reduction but it is still based on a finite fossil fuel. For a climatic sound provision of hydrogen as a fuel electricity from renewable sources of energy like wind or biomass should be used. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.