期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 214, 期 -, 页码 88-94出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2015.05.006
关键词
Methyl blue; Ni-MCM-41; Adsorption; Kinetics; Thermodynamic
类别
资金
- National High-Tech Research and Development Program [2013AA06A305]
- National Natural Science Foundation of China [21347003, 21247004]
- Science & Technology Office of Guangdong Province [2012B031000016]
Adsorbents from Ni functionalized MCM-41 (Ni-MCM-41) were prepared for methyl blue (MB) removal from aqueous solution. The mesoporous structure of Ni-MCM-41 is confirmed by XRD technique. Surface area, pore size and wall thickness are calculated from BET equation and BJH method by nitrogen sorption technique. FT-IR studies show that Ni has been loaded on the hexagonal mesoporous structure of MCM-41. It is found that the MCM-41 structure remains unaltered after the loading of Ni, but its surface area and pore diameter decrease due to pore blockage. The effects of Ni content, adsorbent dosage, initial MB concentration, contact time, pH and temperature on adsorption were investigated. The results indicate that a much higher MB adsorption capacity is achieved by Ni-MCM-41 than MCM-41, and the optimum conditions are identified as: the MB initial concentration of 50 mg/L 0.02 g Ni-MCM-41 with Ni content of 1 wt. % at 25 degrees C and pH value of 6.32. Adsorption of MB on Ni-MCM-41 can be well described by pseudo-second-order kinetics and intra-diffusion model, and equilibrium data is well fitted by Langmuir model. Thermodynamic parameters suggest that the adsorption process is endothermic and spontaneous. The possible adsorption mechanisms might be electrostatic interactions between sulfonic acid groups of MB and the positive Si-O-Ni+ of Ni-MCM-41, and pi-complexation mechanism resulting from the interaction between aromatic cycles of MB and Ni functionality of Ni-MCM-41 might also be plausible. (C) 2015 Elsevier Inc. All rights reserved.
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