期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 214, 期 -, 页码 136-142出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2015.05.021
关键词
Metal organic frameworks (M0Fs); Efficient adsorption; Noncovalent interactions
类别
资金
- National Natural Science Foundation of China [21171148]
- Graduate Student Innovation Project of Zhengzhou University [14LF00620]
The solvothermal reaction of a mixture of bismuth iodide, flexible cationic compound 1,1 ''-(1,4-butanediy1)bis[4,4'-bipyridinium] bis1tetrafluoroborate] (bbpyf) and HI at the temperature of 110 degrees C resulted in a novel compound, namely [bbpy][Bi4I16] (1). The structure of compound 1 was explored with IR spectroscopy, thermal gravimetric analysis (TGA), PXRD, UV-vis diffuse reflectance spectra and singlecrystal X-ray diffraction in the solid state. Compound 1 was a 2D supramolecular structure consisted of one linear cationic compound bbpy(2+) and inorganic anion cluster [B4I16](2-) and contained a channel of 11.214 x 9.727 angstrom via noncovalent interactions. In addition, the adsorption behavior of 1 was also investigated. And it could adsorb methylene blue (MB) and Rhodamine B (RhB) from waste water fast and effectively, highlighting its potential application for environmental issues. (C) 2015 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据