期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 37, 期 8, 页码 7034-7041出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2011.11.067
关键词
Hydrogen production; Methane decomposition; Cobalt catalyst; Effect of catalyst preparation; Carbon formation
资金
- Consejeria de Educacion, Comunidad de Madrid [S-0505/EN/0404 (PHISICO2)]
- Ministerio de Ciencia e Innovacion [ENE2008-05471/ALT]
Hydrogen production by methane decomposition has been studied using different cobalt catalysts obtained by reduction of cobalt oxide precursors synthesized in ethylene glycol and using three different precipitating agents: sodium carbonate, ammonium hydroxide and urea. The physicochemical properties of the catalysts precursors vary with the precipitating agent, which shows a significant influence in their catalytic performance. Thus, the catalysts obtained from precursors precipitated with Na2CO3 or CO(NH2)(2) show remarkable catalytic activity at lower temperatures, which in both cases has been assigned to the lower particle size and aggregation degree of the final metallic Co phase. Accordingly, the use of urea as precipitating agent led to the catalyst with the highest H-2 production at 600 degrees C after 12 h of time on stream. Likewise, it is worth mentioning that the catalyst prepared using Na2CO3 shows significant activity in this reaction even at temperatures as low as 400 degrees C. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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