Optimization of components and assembling in a PEM electrolyzer stack

An optimization study of components and assembling characteristics for a proton exchange membrane (PEM) short stack electrolyzer (3 cells of 100 cm(2) geometrical area) was carried out. The electrochemical properties were investigated by polarization, impedance spectroscopy and chrono-potentiometric measurements. A decrease of the ohmic contact resistance between the bipolar plates and the electrode backing layer was obtained by using an appropriate thickness for the gas diffusion layers/current collectors as well as by an optimization of stack compression. The amount of H-2 produced was similar to 90 1 H-1 at 60 A (600 mA cm(-2)) and 75 degrees C under 300 W of applied electrical power. No significant leakage or gas recombination was observed. The stack electrical efficiency was 75% and 88%, at 60 A and 75 degrees C, with respect to the low and high heating value of hydrogen, respectively. Copyright (C) 2010, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.