期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 36, 期 3, 页码 1939-1948出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2010.11.029
关键词
Preferential oxidation; Carbon nanotube; Platinum; Nickel; Carbon monoxide; Hydrogen
资金
- NSF of China [20976121]
- Chinese 863 program [2006AA05Z115, 2007AA05Z104]
A series of carbon nano-tubes supported platinum-nickel catalysts were prepared and used for CO preferential oxidation in H-2-rich streams. The catalysts were characterized by using N-2-adsorption, XRD, HRTEM, H-2-TPD and H-2-TPR techniques. Effects of platinum and nickel loading amount, CO2 and H2O in the feed stream on the activity and selectivity over the catalysts were investigated. The results of catalytic performance tests show that the carbon nano-tubes supported Pt-Ni catalysts are very active and highly selective at low temperature for CO preferential oxidation in 1 vol. % CO, 1 vol. % O-2, 50 vol. % H-2 and N-2 gases. Adding 12.5 vol. % of CO2 into the feed gases has slight negative influence on CO conversion. Adding 15 vol. % of H2O leads to a little decrease of CO conversion at the temperature range of 100-120 degrees C, which is proposed to be caused by capillary wetting of water in the micro-pores of carbon nano-tubes. As the reaction temperature is higher, adding water can improve CO conversion. The characterization results indicate that platinum species are in nano-particles uniformly dispersed on the carbon nano-tubes surface. There are two kinds of nickel species, one is interacted with platinum and likely to form Pt-Ni alloy in reduction process, the other is much highly dispersed on carbon nano-tubes and strongly interacted with the supports. The high activity of the catalysts is attributed to the interaction between Pt and Ni with the formation of Pt-Ni alloy. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
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