A synthesis of CO-tolerant Nb2O5-promoted Pt/C catalyst for direct methanol fuel cell; its physical and electrochemical characterization

A Pt-Nb2O5/C electrocatalyst was synthesized by a two-step process as an anode material in direct methanol fuel cell (DMFC). The Pt-Nb2O5/C catalysts heat-treated at different temperatures (400 and 500 degrees C) in flowing N-2 were characterized by various methods such as inductively coupled plasma-atomic emission spectroscopy, X-ray diffraction, transmission electron microscopy, and X-ray photoemission spectroscopy (XPS). The heattreated Pt-Nb2O5/C catalyst at 400 degrees C showed the best electrochemical activity for CO and methanol oxidations among the prepared catalysts. The XPS results showed the electronic structure change of Pt, indicating a formation of interaction between Pt and Nb2O5. It is suggested that a synergistic effect between Pt and Nb2O5 enhances the electrocatalytic activity for CO and methanol oxidations. We believe that Nb2O5-promoted Pt/C catalyst may be regarded as one of the attractive candidates as an anode material in DMFC. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.