期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 34, 期 11, 页码 4763-4772出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2009.03.040
关键词
Ni-Cu incipient alloying; Raney-type catalysts; Hydrogen production; Methane decomposition; Carbon nanofibers; Carbon nanotubes
资金
- Fundacao para a Ciencia e a Tecnologia [BD/16035/2004, POCTI/1181]
- FEDER
In the present work, we report on the performance of Ni-Cu alloyed Raney-type catalysts for the production of hydrogen by catalytic methane decomposition. The activity of the catalysts was assessed by comparing the experimental conversions with the calculated equilibrium conversions for each set of experimental conditions. The stability of the catalysts was assessed by comparing the maximum conversions with the conversions at the end of 5 h tests. Comparison with monometallic Ni Raney-type catalytic systems shows that Cu addition significantly improves catalyst stability. Excellent results were obtained when the Ni-Cu Raney-type system was thermally treated in situ at 600 degrees C, as a result of incipient alloy formation. (C) 2009 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
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