Importance of pore size in high-pressure hydrogen storage by porous carbons

Development of high-capacity hydrogen-storage systems utilizing physisorption at high pressure and low temperature is hindered by poor understanding of the pore size/shape requirements for achieving the maximum hydrogen uptake. Tuning the carbon structure and pore size of carbide-derived carbons (CDCs) with high accuracy by using different starting carbides, chlorination temperatures and activation temperatures allows rational design of carbon materials with increased hydrogen-storage capacity. Systematic experimental investigation of a large number of CDCs with controlled pore size distributions and specific surface area (SSA) shows that pores larger than similar to 1.5 nm contribute little to hydrogen storage. It has been experimentally demonstrated that, just as at ambient pressure, pores of 0.6-0.7 nm in diameter provide the largest H(2) uptake per unit SSA at elevated pressures and liquid nitrogen temperatures. The effect of pore size was stronger than the effect of surface chemistry on the hydrogen uptake. (C) 2009 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.