期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 34, 期 1, 页码 147-152出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2008.10.027
关键词
Visible light; Hydrothermal synthesis; Density functional calculations; Hydrogen production; Photocatalyst
资金
- National Natural Science Foundation of China [50802021, 20571019]
- Natural Scientific Research Innovation Foundation in Harbin Institute of Technology (HIT.NSRIF.28)
- Harbin institute of Technology [HITQNJS.2006.028]
- Heilonoang Province Science Foundation for Young Scholar [QC07C18]
- Scientific Research Foundation of Harbin Normal University [KM2007-08]
- Scientific Research Foundation
A series of equivalent substitution solid-solution Na(BixTa1-x)O-3 (x = 0-0. 10) was prepared by a simple hydrothermal method using Ta2O5 and NaBiO3 as precursors. The Na (Bi0.08Ta0.92)O-3 photocatalyst exhibited the highest performance of H-2 evolution (59.48 mu mol h(-1) g(-1)) under visible-light irradiation (lambda > 400 nm) without co-catalyst, whereas no H-2 evolution is observed for NaTaO3 under the same conditions. The UV-Vis spectra indicate that the Na(Bi0.08Ta0.92)O-3 powders can absorb not only ultraviolet light like pure NaTaO3 powder but also the visible-light spectrum. The absorption edge corresponds to a band gap of 2.88 eV. The results of density functional theory calculation illuminate that the visible-light absorption bands in the Na(BixTa1-x)O-3 catalysts are attributed to the band transition from the O2p to the Bi2s + 2p + Ta5d hybrid orbital. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
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