期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 34, 期 17, 页码 7162-7172出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2009.06.076
关键词
Water splitting; Hydrogen; Membrane reactor; Perovskites
资金
- European Network of Excellence [NoE 500895-2]
- Greek Ministry of Industrial Development [05MOXLOS03]
La1-xSrxMO3 (M = Mn, Fe) perovskites are investigated as potential redox materials for the thermochemical production of hydrogen. Thermogravimetric oxidation/reduction experiments indicated that the materials are able to lose and uptake oxygen reversibly from their lattice up to 5.5 wt.% for La1-xSrxMO3 with x = 1 and up to 1.7 wt.% for La1-xSrxFeO3 With x = 0. Pulse reaction experiments indicated that the materials can be used as redox catalysts in a redox process where water is dissociated giving rise to the production of pure hydrogen during the oxidation step. The oxidation and reduction steps can be combined in a membrane reactor constructed from dense perovskite membranes towards a continuous and isothermal operation. The system is also able to operate on partial pressure-based desorption without the need of a carbon-containing reductant, so that a process towards hydrogen production, based only on renewable hydrogen source such as water, can be established. At steady state and 900 degrees C, 25 +/- 7 cm(3) (STP) H-2 m(-2) min(-1) is produced in purified state. (C) 2009 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
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