Electrochemical sensor for nitrite using a glassy carbon electrode modified with gold-copper nanochain networks

Bimetallic gold-copper nanochain networks (AuCu NCNs) were prepared by a single-step wet-chemical approach using metformin as a growth-directing agent. The formation mechanism was investigated in detail, and the AuCu NCNs were characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). The nanocrystals were deposited on glassy carbon electrode and this resulted in a highly sensitive sensor for nitrite. Features include a low working potential (best at 0.684 V vs. SCE), fair sensitivity (17.55 mu A mM(-1)), a wide linear range (0.01 to 4.0 mM), a low detection limit (0.2 mu M, S/N = 3), and superior selectivity as compared to other sensors.