Carbon dioxide storage potential of shales

Options for the geologic storage of carbon dioxide vary from saline aquifers and depleted oil and gas reservoirs to unminable coal seams and abandoned coal mines. Important aspects include the sealing integrity ofthe cap rock and potential changes in this integrity, owing to the interaction with C02. In this study, diffusive transport and gas sorption experiments on one well characterised shale sample (Muderong Shale, Australia) and different clay minerals were performed to obtain information on the sealing integrity and the C02 storage potential of these materials. All measurements were performed under reservoir conditions relevant for C02 storage (T = 45-50 'C; p < 20 MPa). Repeat diffusion experiments on one shale plug yielded increased effective diffusion coefficients and a decrease in the concentration ofthe bulk C02 Volume in the sample. The latter is believed to be dissolved in formation water, sorbed to mineral surfaces or involved with geochemical reactions. For the Muderong Shale, bulk volume C02 concentrations are greater within the experimental time frame (222-389 mol/m'), when compared to coal and cemented sandstone (3-4 and 8-10 MoUrn), respectively. This high C02 storage potential could not fully be explained by C02 dissolution in water alone. Thus, gas sorption experiments were performed on crushed shale and various clay minerals. High C02 sorption capacities (e.g. up to I mmoVg for the Muderong Shale) show that the high C02 concentration is related to a combination Of C02 dissolution in water and gas sorption on clay minerals. Additionally, changes in specific surface areas before and after the sorption experiments and variations in the C02 sorption and diffusion behaviour due to repetitive experiments on the identical sample were observed, possibly related to geochernical alteration of the Muderong Shale and the clay minerals. These could not be quantified however and seemed to occur only at high pressures. Results obtained in this study provide a more positive view on the sealing integrity of intact cap rock formations. Carbon dioxide that migrates from a storage reservoir into the cap rock through the pore network will be immobilised to a certain extent, hence minimising (slow, diffusion- driven) leakage and providing additional C02 storage potential. (c) 2008 Elsevier Ltd. All rights reserved.