期刊
INTERMETALLICS
卷 17, 期 3, 页码 165-168出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.intermet.2008.10.012
关键词
Oxidation; Glasses, metallic
资金
- National Science and Council of Republic of China [NSC-96-E-2218-110-001]
- Division of Materials Science and Engineering
- Office of Basic Energy Sciences
- US Department of Energy
The oxidation behavior of an Fe61B15Zr8Mo7Co5Y2Cr2 bulk metallic glass (Fe7-BMG) was investigated in three oxygen-containing atmospheres over the oxygen partial pressure range of 10(3)-10(5) Pa at 650 degrees C. The oxidation kinetics of the Fe7-BMG followed the parabolic rate law in all cases, indicating that solid-state diffusion is the rate-controlling step during oxidation. The oxidation rate constants (k(p) values) increased with increasing oxygen partial pressure, implying a typical scaling behavior with a p-type semi-conductivity. Duplex scales formed on the Fe7-BMG consisted of an outer layer of mostly iron oxides (Fe2O3/Fe3O4) and minor amounts of B2O3, and a heterophasic inner layer of mostly tetragonal-ZrO2 (t-ZrO2) intermixed with non-oxidized intermetallic phases. (C) 2008 Published by Elsevier Ltd.
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