期刊
INORGANICA CHIMICA ACTA
卷 483, 期 -, 页码 71-78出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2018.07.035
关键词
Copper coordination chemistry; Oxidation reactions; Complex characterization; O-O bond cleavage mechanism; Cumyl hydroperoxide
资金
- University of Alabama in Huntsville
- National Science Foundation [CHE - 1626172]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences, under National Laboratory [DE-AC02-06CH11357]
Cu(II) complexes bearing N2/Py2 tetradentate ligands consisting of two pyridyl arms and a flexible ethyldiamine backbone, [(BPMEN)Cu(ClO4)(2)] (1), with rigid cyclohexyl backbone [(BPMCN)Cu(ClO4)(2)] (2), and substituted with bispyrrolidyl [(PDP)Cu(ClO4)(2)] (3), and Cu(II) complex bearing N2/Py3 pentadentate ligand, [(TPMEN)Cu(ClO4)(2)] (4), were synthesized and structurally characterized. Reactivity of 1-4 with cumyl hydroperoxide was investigated to study the effects of ligand rigidity and denticity on the mechanism of O-O bond cleavage. Results presented herein illustrate that 1-3 favors homolysis, however 4 showed little to almost no impact on O-O bond cleavage.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据