期刊
INORGANICA CHIMICA ACTA
卷 409, 期 -, 页码 238-243出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2013.09.024
关键词
Dicarboxamide-diphosphine; Gold(I); Silver(I); Supramolecular assembly
资金
- NSERC (Canada)
The dicarboxamide-diphosphine ligand N,N'-bis(2-diphenylphosphinoethyl)phthalamide, dpppa, which is prepared from 2-diphenylphosphinoethylamine and phthaloyl chloride, forms the binuclear gold(I) complex [Au2Cl2(mu-dpppa)], 1, and polymeric complex [{Ag-2(mu-O2CCF3)(2)(mu-dpppa)}(n)], 2. The ligand and both complexes 1 and 2 undergo further association through hydrogen bonding to give supramolecular polymer or network structures. (C) 2013 Elsevier B.V. All rights reserved.
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