期刊
INORGANICA CHIMICA ACTA
卷 363, 期 2, 页码 430-437出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2009.11.015
关键词
N-heterocyclic carbene; Ruthenium(II); Carbonyl; Catalyst; Transfer hydrogenation
资金
- National Natural Science Foundation of China (NSAF) [10676012]
- National Basic Research Program of China [2006CB806104, 2007CB925102]
- US National Science Foundation [CHE-051692]
In this contribution, the synthesis and characterization of eight ruthenium(II) carbonyl complexes supported by chelating alkane-bridged bis-N-heterocyclic carbene ligands are reported. The products obtained are analyzed using infrared and NMR spectroscopies. The molecular structures of four metal complexes were determined by X-ray crystallography, which exhibit the six-coordinate octahedral geometry with two carbene carbon atoms from the bidentate Bi-NHCs, two carbonyl groups and two chlorine atoms in the trans(Cl)-cis(CO) configuration. All these complexes show catalytic activities in transfer hydrogenation of ketones. (C) 2009 Elsevier B. V. All rights reserved.
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