期刊
INORGANICA CHIMICA ACTA
卷 363, 期 6, 页码 1306-1310出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2010.02.003
关键词
Cross coupling reactions; Suzuki-Miyaura couplings, palladium complexes; Palladacycles, pincer compounds; Crystal structures; Catalysis
资金
- CONACYT [F58692]
- DGAPA-UNAM [IN227008]
The reaction of 3-mercaptophenol with diphenylchlorophosphine in a 1:2 ratio in the presence of NEt3 as base, affords cleanly the non-symmetric ligand [C6H4-1-(SPPh2)-3-(OPPh2)](1). The direct reaction of this ligand with PdCl2 in refluxing toluene affords the non-symmetric phosphinito-thiophosphinito PSCOP pincer complex [PdCl{C6H3-2-(SPPh2)-6-(OPPh2)}](2). (C) 2010 Elsevier B. V. All rights reserved.
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