4.5 Article

Unusual lithium coordinated platinum and rhodium hydride dimers

期刊

INORGANICA CHIMICA ACTA
卷 363, 期 3, 页码 517-522

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2009.05.013

关键词

Platinum complexes; Rhodium complexes; Hydride complexes; X-ray crystal structures

资金

  1. National Science Foundation [CHE-0717040]

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Two unusual lithium coordinated binuclear platinum- and rhodium-hydride complexes [M(dip-pe)(H)](2)center dot LiHBEt3 were synthesized and characterized by NMR spectroscopy and X-ray crystallography. Not only does the lithium ion interact with the metal hydrides, but also with the B-H bond of the borohydride. (C) 2009 Elsevier B. V. All rights reserved.

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