期刊
INORGANICA CHIMICA ACTA
卷 362, 期 6, 页码 2076-2079出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2008.09.009
关键词
Spin crossover; Crystal structures; Magnetic properties; Ligands; Iron(III)
资金
- Fundacao para a Ciencia e Tecnologia (Portugal) [PTDC/QUI/65379/2006, SFRH/BPD/21873/2005]
- Fundação para a Ciência e a Tecnologia [SFRH/BPD/21873/2005, PTDC/QUI/65379/2006] Funding Source: FCT
Compounds Fe-III(3-CH3O-qsal)(2)PF6 center dot nH(2)O (n = 0, 2) (1, 1 center dot 2H(2)O) were synthesized and characterized: the structure of 1 and the magnetic properties of both compounds were determined. Compound 1 center dot 2H(2)O presents properties characteristic of high-spin Fe(III), while 1 presents properties of low-spin Fe(III) with an onset of a gradual spin crossover at ca. 300 K. (C) 2008 Elsevier B.V. All rights reserved.
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