期刊
INORGANICA CHIMICA ACTA
卷 362, 期 6, 页码 1952-1956出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2008.09.031
关键词
6-Hydroxynicotinic acid; Cadmium complex; Hydrothermal synthesis; Luminescent property; NLO-active
资金
- Natural Sciences Foundation of Zhejiang Province [Y406355]
Employing an unsymmetrical 6-hydroxynicotinic acid as a bridging ligand, we have prepared a new NLO-active two-dimensional cadmium coordination polymer [Cd-8(nicO)(8)(phen)(8) center dot (H2O)](n) (1) (H(2)nicO = 6-hydroxynicotinic acid, phen = 1,10-phenanthroline) under hydrothermal condition. At room temperature, 1 shows strong fluorescent emission bands in the solid state and a SHG efficiency of about 8 times that of KDP (KH2PO4). On the basis of TG/DTA analyses, the structure is thermally stable up to 370 degrees C. (c) 2008 Elsevier B.V. All rights reserved.
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