期刊
INORGANICA CHIMICA ACTA
卷 362, 期 4, 页码 1169-1178出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2008.06.007
关键词
Macrocyclic ligands; Fluorescent probes; UV-Vis and fluorimetric titrations; Zn2+; Cu2+
The Zn2+ and Cu2+ complexes of L-1 and L-2 ligands (L-1: 1-(benzimidazol-2-ylmethyl)-1,4,7,10-tetraazacyclododecane, L-2: 1,7-bis(benzimidazol-2-ylmethyl)-1,4,7,10-tetraazacyclododecane) were synthesised and characterised by means of NMR, EPR, and UV-Vis spectroscopies, X-ray determination and molecular modelisation (HF-DFT(B3LYP)/LANL2DZ). These studies showed that the 1: 1 complexes were formed in which the benzimidazole arm(s) are coordinated to the metal ion. On addition of successive amounts of Zn2+ in CH3CN, the. fluorescence emission of L-1 increased linearly by a factor of 50 and the one of L-2 by a factor of 5 while on addition of successive amounts of Cu2+ in CH3CN, the. fluorescence emission of L-2 decreased linearly to 80% of its initial value. (C) 2008 Elsevier B. V. All rights reserved.
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