期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 35, 期 -, 页码 355-359出版社
ELSEVIER
DOI: 10.1016/j.inoche.2013.07.009
关键词
BODIPY; Fluorescence; Cu+ detection; Crystal structure; Suzuki coupling; Imaging
资金
- National Basic Research Program [2011CB808704]
- National Natural Science Foundation of China [21071075, 20931004]
Two new pyridine-substituted boron-dipyrromethene (BODIPY) dyes have been synthesized via the Suzuki coupling reactions of 2,6-diiodo-1,3,5,7-tetramethyl-8-methyl-4,4-difluoroboradiazaindacene and respective pyridinylboronic acid. The molecular structures of the two title compounds have been determined by single-crystal X-ray diffraction analyses. The absorption and steady-state fluorescent properties in different solvents were investigated, which showed that the two compounds are highly fluorescent with a relatively small Stokes shift, high fluorescent quantum yields and little solvent dependence, similar to other BODIPY chromophores. The fluorescence of two compounds were highly sensitive towards Cu+, owing to significant interactions between Cu+ and the nitrogen atoms on the pyridine rings. (C) 2013 Elsevier B.V. All rights reserved.
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