期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 20, 期 -, 页码 27-29出版社
ELSEVIER
DOI: 10.1016/j.inoche.2012.02.006
关键词
Luminescence; Palladium(0); Phosphine complexes
资金
- Strategic Research Base Development Program for Private Universities
- Ministry of Education, Culture, Sports, Science & Technology in Japan [21550067]
- Grants-in-Aid for Scientific Research [21550067] Funding Source: KAKEN
Photoluminescence properties of palladium(0) complexes bearing monodentate phosphines are described. [Pd(P(o-tol)(3))(2)] (o-tol = ortho-tolyl) emits relatively strong blue luminescence in the solid state. Whereas, [Pd(PCyPh2)(3)] (Cy = cyclohexyl) and [Pd(PCy3)(2)] show orange luminescence with a large Stokes-shift. The crystal structure analysis of [Pd(PCyPh2)(3)] reveals the trigonal planar geometry around the palladium atom. (C) 2012 Elsevier B.V. All rights reserved.
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