期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 15, 期 -, 页码 198-201出版社
ELSEVIER
DOI: 10.1016/j.inoche.2011.10.023
关键词
H(3)thme; Coordination polymer; Mn (III)/Na (I) cluster; Magnetic property
资金
- State Key Laboratory of Structural Chemistry
- Institute of Research on the Structure of Matter
- Chinese Academy of Sciences
- National Basic Research Program of China (973 Program) [2012CB821702]
- National Natural Science Foundation of China [20733003, 20903096]
- Key laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences [2011KL007]
A new 2D polymer, {[Mn6Na3(mu(6)-O)(thme)(4)(PhCO2)(6)(mu-H2O)(3)][OH]}(n) (1), has been synthesized and characterized by single crystal X-ray diffraction, XRD, IR spectroscopy, thermogravimetric analysis (TGA) and magnetic measurements. Compound 1 has a 2D honeycomb-like structure constructed by heterometallic {Mn6Na3} clusters, which are linked by water molecules cross-bridged between the Na (I) ions of the adjacent clusters. Magnetic property study reveals the existence of antiferromagnetic couplings between Mn (III) ions within the (Mn6Na3) clusters. (C) 2011 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
